Table A.1: Fitting coefficients of HC3N-para-H2(J2 = 0) rates, following formula (5). J1 and J'1 are the initial and final rotation states, respectively. The rates thus obtained are in cm^3s^-1 . Rates are quantum for J1up<=15, classical otherwise. ================================================================== J1 J'1 a(0) a(1) a(2) a(3) a(4) ------------------------------- 1 0 -25.51832 106.88002 -291.58814 350.10316 -154.84199 2 0 -24.35512 106.84051 -287.22039 328.93070 -136.65661 2 1 -14.61936 33.10754 -100.86405 134.46313 -64.92410 3 0 -5.47571 -35.76987 79.22847 -71.33148 21.84669 3 1 -14.72047 37.31354 -99.10777 109.36028 -43.08167 3 2 -10.28982 0.65318 -9.29094 22.34848 -14.56401 4 0 -7.41774 -26.73297 82.55022 -109.01113 51.70164 4 1 -3.38680 -51.59920 129.83555 -139.00247 54.24922 4 2 -15.21990 38.99699 -97.70381 101.86978 -37.80211 4 3 -12.58261 16.11524 -46.07311 59.69880 -28.32805 5 0 -2.57002 -65.02497 173.34352 -196.93477 81.38532 5 1 -6.70478 -32.22515 104.01102 -141.22086 68.20796 5 2 -7.77688 -20.41374 51.00900 -52.23946 18.89396 5 3 -14.68567 35.11227 -86.12083 86.29616 -30.00840 5 4 -16.11594 42.59701 -118.20463 145.03851 -65.46450 6 0 -6.13685 -45.36061 149.75974 -205.86434 100.21101 6 1 -8.64971 -19.59865 56.44070 -66.00344 27.12532 6 2 -10.28772 -6.27935 36.89117 -65.85667 37.18314 6 3 -9.22466 -8.43687 17.48400 -12.41144 1.57029 6 4 -15.64671 43.10487 -109.73894 116.17416 -43.72905 6 5 -14.41336 32.47142 -95.78570 123.12942 -57.48288 7 0 -10.78341 -11.00360 42.71396 -62.38185 30.99555 7 1 -8.47134 -26.73320 103.12673 -156.24676 81.04140 7 2 -10.52514 -4.01783 14.11252 -17.79053 7.37242 7 3 -12.46550 11.17004 -13.17720 -3.74494 8.97429 7 4 -11.11202 7.70446 -30.98603 49.78866 -27.50257 7 5 -14.11456 32.83262 -84.04719 87.74861 -31.92234 7 6 -12.88796 23.22698 -75.25517 103.35455 -50.51406 8 0 -13.38837 0.02904 45.02589 -106.11757 66.91335 8 1 -16.15190 32.15754 -74.52365 74.52728 -27.21444 8 2 -12.41248 4.26702 16.28624 -50.87715 34.08956 8 3 -9.57815 -6.79964 13.57592 -9.78042 1.47624 8 4 -11.37909 4.75157 0.91307 -17.25883 13.85036 8 5 -8.91813 -5.80461 0.00434 18.44041 -15.62564 8 6 -18.13303 61.83878 -162.03735 180.33365 -72.79000 8 7 -9.90163 2.74864 -23.17369 45.17610 -26.51891 9 0 -29.82574 126.14490 -320.70118 353.45960 -143.05848 9 1 -16.43119 25.24029 -21.82079 -31.50924 36.98088 9 2 -18.13932 52.53034 -140.54421 163.21878 -69.81489 9 3 -11.60134 0.93022 19.76559 -49.25968 31.21266 9 4 -7.10154 -21.85393 47.93692 -44.39906 14.48424 9 5 -10.93830 2.33916 5.51949 -20.60739 14.54558 9 6 -5.02685 -32.82491 70.20632 -62.34203 19.12060 9 7 -14.24666 34.75272 -91.84970 100.19874 -38.71027 9 8 -7.79979 -12.45038 17.57024 -2.84443 -5.50013 10 0 -30.74777 114.05664 -225.51866 159.18442 -22.70276 10 1 -39.00410 200.75846 -532.95664 614.99802 -261.48335 10 2 -20.07566 54.80765 -106.43261 72.62945 -9.70628 10 3 -11.92876 11.94117 -40.44338 53.65904 -24.88768 10 4 -11.48476 1.42081 15.41256 -40.84799 26.37924 10 5 -3.85593 -43.46421 101.73389 -103.45405 38.59973 10 6 -11.31632 5.13387 -2.08303 -11.54640 10.66508 10 7 -3.67891 -43.12965 99.45931 -98.69278 35.76283 10 8 -13.90765 32.55352 -86.78912 95.40806 -37.14244 10 9 -6.60948 -21.44139 42.44674 -32.69685 7.57630 11 0 -69.08122 420.33417 -1134.19665 1332.58368 -577.17783 11 1 -40.26915 186.66520 -420.43692 385.05400 -118.45036 11 2 -37.90099 199.69566 -543.57701 640.21840 -276.73796 11 3 -20.14212 57.23802 -117.06233 89.62936 -18.81605 11 4 -9.67380 -0.68862 -15.15065 33.12554 -19.54264 11 5 -10.03000 -8.79385 42.23006 -71.83318 39.81500 11 6 -2.01512 -55.97720 133.45404 -138.83443 53.27885 11 7 -11.89745 9.29782 -13.14465 1.40714 5.11882 11 8 -3.52867 -44.91918 105.98087 -108.06217 40.38518 11 9 -16.98632 54.81510 -146.87723 167.18816 -69.11154 11 10 -6.27560 -24.43393 51.55426 -44.02788 12.42472 12 0 -110.08999 671.89795 -1673.39792 1794.52580 -702.20758 12 1 -79.23534 502.83570 -1369.45426 1623.10507 -709.17840 12 2 -43.96236 217.92588 -514.17089 506.98652 -176.78861 12 3 -31.26580 155.56616 -432.99781 517.61009 -226.10646 12 4 -15.66040 26.43792 -38.38127 1.62187 17.68910 12 5 -1.69568 -57.81035 137.41382 -146.62275 59.33281 12 6 -11.49393 1.85124 13.25291 -36.70366 23.97437 12 7 -1.30588 -61.40897 148.81232 -157.61190 61.64585 12 8 -13.30200 19.28527 -39.60948 32.39554 -8.32782 12 9 -3.93283 -42.70787 101.73134 -104.66734 39.48733 12 10 -14.58397 37.83552 -102.22653 115.34221 -46.61063 12 11 -6.84937 -20.88700 43.27719 -35.20778 8.76813 13 1 -121.42176 760.23690 -1919.78115 2095.24554 -838.35388 13 2 -73.43881 466.18432 -1280.50008 1526.86938 -670.24329 13 3 -37.46863 173.69762 -402.14277 383.07082 -126.22192 13 4 -25.11786 113.32185 -324.75123 395.89658 -175.53626 13 5 -16.31200 31.34417 -52.45879 20.16637 8.53283 13 6 -5.03111 -34.19360 74.82450 -72.55575 26.24645 13 7 -12.26751 7.51849 -2.38408 -17.31497 14.98484 13 8 -1.77878 -58.36783 141.41142 -149.22379 57.81292 13 9 -14.07839 25.17746 -56.25427 53.14293 -17.88514 13 10 -5.10621 -35.30788 84.48831 -86.84162 32.48677 13 11 -15.68430 45.37443 -121.47165 137.06234 -55.70906 13 12 -7.63435 -15.76136 30.71303 -21.37272 2.94020 14 1 -117.52398 791.58601 -2171.95252 2593.52489 -1142.29451 14 2 -101.97192 622.81734 -1556.51667 1672.17066 -655.34871 14 3 -64.97054 407.56112 -1127.80646 1350.92195 -594.71729 14 4 -33.40083 146.10829 -333.38038 309.34404 -97.51001 14 5 -22.24962 93.16380 -272.14826 336.05107 -150.44281 14 6 -15.97667 29.69922 -50.66280 22.10118 5.65358 14 7 -5.12027 -33.46409 72.46275 -68.78901 23.94264 14 8 -13.51141 16.62484 -27.36720 13.21097 1.11568 14 9 -2.85727 -51.51845 125.40322 -132.75179 51.47909 14 10 -14.81190 30.52822 -70.95472 71.18866 -26.15235 14 11 -6.25020 -27.64004 65.46158 -66.06082 24.03841 14 12 -16.86546 54.18749 -146.19281 167.84696 -69.99618 14 13 -9.39251 -3.93229 1.12685 11.39170 -10.73118 15 1 -187.76520 1243.63911 -3227.93849 3646.24535 -1519.57337 15 2 -112.58143 761.87334 -2104.01237 2525.18121 -1116.95420 15 3 -91.55082 548.48401 -1358.90665 1441.31923 -555.11323 15 4 -58.16941 359.46429 -1000.87810 1203.64034 -531.23265 15 5 -32.30239 138.91568 -316.64601 293.68577 -92.56396 15 6 -21.24176 85.02826 -248.35224 306.26621 -136.65828 15 7 -18.24773 46.22364 -95.83431 77.23616 -19.43065 15 8 -3.51225 -45.76402 106.93734 -110.49496 42.36352 15 9 -14.62984 24.72653 -49.48991 40.26732 -11.24332 15 10 -4.90746 -38.05020 92.52413 -97.23545 37.19573 15 11 -15.83536 37.88336 -90.78815 94.98344 -36.82878 15 12 -6.63674 -25.75461 62.34128 -63.76717 23.19492 15 13 -19.26132 71.66204 -193.76205 225.08345 -95.66104 15 14 -8.52544 -10.93663 21.95643 -15.56076 2.01564 16 1 2073.89337 -14655.06952 38446.56275 -44649.89192 19359.13030 16 2 -698.15542 4823.68370 -12519.96132 14235.30139 -5999.43022 16 3 -1266.41777 9036.67298 -24241.43039 28724.19981 -12697.95692 16 4 -458.51447 3197.51847 -8512.88000 10008.91118 -4392.75851 16 5 274.00544 -2014.02376 5304.88427 -6174.06457 2676.35074 16 6 -14.27306 106.95039 -489.92832 798.35342 -440.60154 16 7 -264.91830 1823.39524 -4860.10567 5706.44129 -2492.81571 16 8 -36.31032 158.17019 -353.45048 335.77150 -113.16458 16 9 79.93056 -643.90150 1711.67152 -2012.44228 881.86193 16 10 -84.44641 531.88147 -1422.48660 1679.31253 -738.82137 16 11 -46.42216 260.12543 -697.05290 823.92074 -362.77668 16 12 -82.79534 524.16306 -1406.20954 1661.91042 -730.39693 16 13 18.93955 -221.71427 630.59099 -790.38109 367.95194 16 14 60.59096 -503.09882 1338.49056 -1574.75274 691.15235 16 15 -74.88622 478.79648 -1301.57719 1553.58472 -688.35113 17 2 117.37789 -505.38058 347.20929 608.39922 -652.81492 17 3 -1371.02786 9920.79652 -26817.34279 31830.11048 -14017.67612 17 4 -206.21826 1347.69601 -3458.46579 3914.95462 -1665.40935 17 5 -283.06486 1853.18922 -4653.51988 5097.50760 -2058.91887 17 6 92.82350 -756.42502 2068.08084 -2509.26625 1135.05563 17 7 -24.19152 102.13131 -274.22996 309.78787 -127.16171 17 8 -271.23783 1812.13791 -4690.41209 5358.38195 -2283.01426 17 9 51.11578 -459.96725 1273.07267 -1551.30815 701.34767 17 10 8.48732 -125.23408 307.19333 -332.08725 133.16815 17 11 -57.43650 331.30479 -872.70994 1018.48718 -444.17876 17 12 113.69137 -881.39318 2332.98179 -2726.42447 1187.39902 17 13 -96.42097 615.29675 -1634.82029 1916.29144 -836.11570 17 14 184.53257 -1376.95394 3631.21874 -4231.07672 1838.23260 17 15 20.14809 -191.93225 455.02942 -475.94319 185.37764 17 16 -75.49937 469.40668 -1241.05521 1443.23465 -624.27240 18 4 -1062.05521 7552.66023 -20110.91574 23508.76040 -10197.46234 18 5 152.79431 -1489.28772 4884.13036 -6896.68249 3541.54426 18 6 241.60328 -1756.63875 4569.19000 -5270.90135 2269.97895 18 7 235.46868 -1776.08490 4789.99335 -5723.93297 2551.01675 18 8 -343.69880 2340.84398 -6117.97626 7042.40497 -3014.72475 18 9 88.11381 -756.92330 2149.19487 -2680.84646 1238.28533 18 10 122.80049 -940.30288 2473.30625 -2877.67706 1248.79905 18 11 84.51405 -673.65071 1776.61370 -2066.10155 893.79866 18 12 97.57784 -773.84537 2066.23602 -2436.21315 1070.14202 18 13 -134.89406 874.11969 -2288.04235 2648.81475 -1144.52168 18 14 171.93020 -1289.03959 3401.63219 -3967.11789 1725.41911 18 15 -90.68065 593.07025 -1622.80060 1956.74348 -877.14293 18 16 -50.19982 301.75703 -837.77739 1021.62923 -462.14167 18 17 6.02542 -104.95067 267.85159 -309.14692 134.87592 19 4 -1068.11296 7460.15389 -19543.17053 22507.76781 -9630.71099 19 5 -361.88593 2550.94200 -6805.67359 7892.26822 -3373.92306 19 6 -336.19081 2658.16220 -7951.65745 10355.75647 -4979.29469 19 7 -241.79058 1700.60986 -4649.25589 5588.93407 -2498.45652 19 8 -298.59733 1971.73342 -5028.45576 5659.10849 -2376.89343 19 9 258.53018 -1930.50715 5155.06224 -6075.76791 2663.43620 19 10 126.54378 -1004.43059 2743.07766 -3312.48892 1490.63371 19 11 -119.49514 754.44028 -1952.43954 2237.91604 -959.50920 19 12 -62.65451 349.28128 -876.97857 978.15593 -408.93286 19 13 169.82736 -1272.09194 3346.33721 -3888.84402 1684.86657 19 14 10.03155 -133.84773 327.03338 -351.04088 139.62640 19 15 -36.52434 195.28543 -534.39455 639.44170 -282.24329 19 16 1.15577 -85.44081 240.77925 -298.28997 137.17470 19 17 -52.91035 311.89785 -841.01323 998.65753 -440.90458 19 18 6.30942 -97.89757 222.90917 -223.06526 81.60545 20 5 -1092.86958 8133.95666 -22597.56110 27489.60234 -12378.73735 20 6 -690.14356 4645.43353 -11731.48176 12948.88675 -5283.21228 20 7 -462.67518 3154.66150 -8175.98034 9311.95613 -3939.34593 20 8 252.09771 -1873.73823 4996.11835 -5910.61245 2611.60398 20 9 -513.40952 3649.04932 -9860.89874 11754.11974 -5218.80027 20 10 11.22683 -139.01688 339.49461 -382.58804 165.65485 20 11 -160.61722 1043.39775 -2705.73394 3098.23161 -1322.94571 20 12 151.69809 -1171.17152 3147.47088 -3733.61062 1649.11198 20 13 179.94541 -1355.43399 3598.71801 -4224.11854 1849.16748 20 14 64.44229 -535.41079 1425.43443 -1673.53297 731.06078 20 15 67.04543 -555.65363 1490.42556 -1768.63994 783.39552 20 16 -126.72327 819.22237 -2146.79511 2485.86313 -1073.17499 20 17 -131.45472 878.54495 -2367.70258 2815.41424 -1246.17098 20 18 20.34383 -211.62099 550.89903 -633.28077 271.00912 20 19 106.32388 -820.78536 2168.18463 -2533.17780 1103.24490 21 6 -396.04084 2707.31199 -7008.80423 7900.63877 -3284.43982 21 7 -797.94902 5568.10111 -14603.90154 16815.74936 -7188.20217 21 8 104.02906 -1111.00043 3794.26444 -5514.66816 2891.02772 21 9 -379.22779 2711.09012 -7421.05783 8953.72254 -4024.63727 21 10 106.97020 -863.24346 2374.84030 -2905.79721 1329.29051 21 11 -295.50438 2091.84461 -5699.40433 6826.53646 -3036.01147 21 12 36.09375 -313.58721 790.63293 -888.23900 373.80363 21 13 -125.42563 839.01699 -2283.11585 2741.93844 -1226.55106 21 14 132.65392 -1012.98000 2669.47442 -3104.05929 1343.69910 21 15 -65.33903 384.06044 -999.77924 1148.73484 -491.33493 21 16 -60.20245 331.77670 -819.24991 890.04860 -358.49283 21 17 74.78889 -597.83982 1568.02567 -1817.08191 785.11873 21 18 101.27811 -796.48686 2124.27212 -2504.02792 1100.95205 21 19 2.29053 -88.32898 237.36292 -280.67821 122.95873 21 20 2.62265 -66.49764 127.28807 -97.77772 21.54784 22 7 -3408.65715 24143.70871 -63840.23361 74429.78838 -32301.22363 22 8 1263.84082 -8934.94142 23331.65979 -26917.35666 11566.92278 22 9 -349.94892 2665.41053 -7773.47899 9970.69104 -4756.90347 22 10 -111.57437 719.54792 -1900.83467 2203.83721 -953.85518 22 11 -277.87411 1906.72551 -5070.17528 5950.58727 -2604.38441 22 12 -202.92832 1383.42614 -3708.16568 4387.72310 -1936.78971 22 13 -33.56219 169.35446 -462.80402 553.58919 -245.70905 22 14 -115.41636 746.41100 -1974.37838 2300.77194 -997.62768 22 15 -115.80405 737.83554 -1923.78241 2212.61970 -947.22469 22 16 -157.83215 1041.62821 -2741.91680 3188.56097 -1382.32448 22 17 -109.87652 702.50094 -1848.03780 2148.67780 -931.34544 22 18 45.21210 -412.89111 1145.02344 -1400.21172 637.23775 22 19 62.88926 -490.03654 1224.36560 -1349.37837 553.86363 22 20 -45.78281 259.18757 -695.41791 820.80369 -359.96111 22 21 -23.06715 116.11616 -357.59784 471.14033 -227.18411 23 8 -2181.44690 15698.24223 -42174.61732 49865.49134 -21912.21039 23 9 -257.04756 1651.31466 -4015.81237 4169.26525 -1561.57067 23 10 -266.89847 1779.33500 -4569.38398 5126.86687 -2124.06129 23 11 60.17208 -486.08132 1257.58797 -1462.24051 639.95616 23 12 -28.08944 81.03985 -102.05168 -17.90737 67.74493 23 13 219.45359 -1607.70732 4174.62923 -4777.44504 2031.30292 23 14 283.25877 -2071.73595 5452.25532 -6349.06385 2758.75798 23 15 -97.69814 645.27498 -1769.07041 2128.94829 -949.75642 23 16 -59.94507 357.67492 -960.23934 1135.05914 -498.58268 23 17 -93.01639 596.56628 -1604.77287 1905.98352 -843.01336 23 18 -49.88335 281.00993 -737.68586 849.50314 -362.01797 23 19 -19.73708 74.95899 -214.25977 266.84461 -122.56251 23 20 76.65441 -621.73962 1662.03988 -1962.86013 864.05955 23 21 -8.60437 -23.76177 103.56856 -170.11091 95.25838 23 22 81.44132 -640.60203 1682.99915 -1957.09361 848.68295 24 9 287.09907 -2134.67134 5776.32085 -7010.38333 3198.28258 24 10 -965.15204 6937.13835 -18745.67500 22310.11627 -9883.27294 24 11 -438.82019 3141.08710 -8556.66452 10249.58339 -4563.26429 24 12 -176.82153 1203.04512 -3229.27202 3801.01170 -1659.54477 24 13 154.51680 -1175.61601 3122.31963 -3669.90509 1606.73578 24 14 -108.73955 699.27717 -1851.32498 2156.18589 -934.32383 24 15 74.11457 -595.85477 1566.78428 -1826.19610 794.89197 24 16 -5.69208 -63.06908 248.29298 -390.58497 214.96346 24 17 147.77279 -1135.35191 3037.24619 -3590.20560 1582.29011 24 18 -86.34978 539.29630 -1425.78321 1664.66184 -724.05677 24 19 45.59527 -415.58438 1148.41714 -1397.28528 631.79950 24 20 -30.84298 144.90169 -376.19916 428.82513 -180.79960 24 21 -26.35735 115.17997 -301.31647 345.51761 -146.38722 24 22 -85.16701 540.69678 -1445.89907 1705.98521 -749.85166 24 23 68.32281 -543.64961 1416.77649 -1635.09544 703.88006 25 10 638.29214 -4806.40309 13295.88004 -16282.72737 7426.36872 25 11 -836.64186 6043.58082 -16463.20058 19785.15258 -8864.73409 25 12 1107.68668 -8044.12755 21585.23189 -25610.23116 11326.76210 25 13 -266.74355 1922.32996 -5367.74471 6604.22203 -3025.77152 25 14 259.31310 -1930.01145 5149.50397 -6079.44225 2676.38578 25 15 -120.17922 804.62041 -2194.59025 2633.92750 -1176.14654 25 16 -187.32932 1260.55438 -3347.39813 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